To activate the following cheats, enter the Urahara shop and go to the password menu. Then, perform the corresponding actions on the touchscreen:

100,000 Kan for the Urahara Shop for Chappy - Draw five large counter-clockwise circles.
100,000 Kan for the Urahara Shop for Jar - Draw five large clockwise circles.

Unlock the following characters by performing the corresponding tasks:

Aizen Sousuke - Beat Story mode Part A.
Bonnie - Defeat Bonnie in Story mode.
Don Kanonji - Beat Story mode Part D.
Goteitaishi - Beat Story mode Parts A through D 100%.
Grandfisher - Beat Story mode Parts A through D 100%.
Hollows - Beat Story mode 100%.
Ichimaru Gin - Beat Story mode Part B 100%.
Iduru Kira - Defeat him and Rangiku together in Story mode.
Kukaku - Beat Story mode Part B.
Kyugohanin - Beat Story mode Parts A through D 100%.
Menos-Grande - Beat Story mode Parts A through D 100%.
Ogihci - Beat Story mode Part C 100%.
Rangiku Matsumoto - Defeat her and Iduru together in Story mode.
Ririn - Beat Story mode Part D 100%.
Rukia Kuchiki - Beat the first part of Story mode.
Shibata - Beat Story mode Parts A through D 100%.
Shrieker - Beat Story mode Parts A through D 100%.
Shuhei Hisagi - Defeat him in Story mode.
Soifon - Defeat her in Story mode.
Tatsuki - Beat Story mode Part C 100%.
Tosen - Beat Story mode Part A 100%.
Tsukaima - Beat Story mode Parts A through D 100%.
Ururu - Beat Story mode Part A.
Yachiru Kusajishi - Defeat her in Story mode.