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Get Monsters: Get Empyrea - Catch each monster. Get Grandpa Slime - Catch any two-hundred monsters. Get Leopold - Get each skill. Get Liquid Metal Slime - Catch one-hundred monsters. Get Metal Kaiser Slime - Catch one-hundred fifty skills. Get Metal King Slime - Catch one-hundred skills. Get Robbin' Hood - Catch each monster and acquire each skill.
Get Rank S: Have a level 10 Demon-at-Arms and Buffalogre. Go to the Scout Post and speak to the person who does the syntheses. Choose the 2 monsters (one monster must be +, the other -) and you’ll be able to select the Rank S monster and synthesize it.
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