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Characters: Beat Crocodile in Luffy's adventure mode to unlock Buggy and Mr. 0 Crocodile's adventure mode, continue with Luffy's adventure and defeat Eneru to unlock Chaser's adventure mode.
Nico Robin: I n Luffy's adventure mode, use her once in battle after she joins the crew.
Red-Haired Shanks: In Buggy's adventure mode, use him once in battle after he joins the crew.
Portgaz D. Trace: In Buggy's adventure mode, use him once in battle after he joins the crew.
Mr. 2 Bon Clay: In Mr. 0 Crocodile's adventure mode, use him once in battle after he joins the crew.
Ohm: In Mr. 0 Crocodile's adventure mode, use him once in battle after he joins the crew.
Eneru: In Mr. 0 Crocodile's adventure mode, use him once in battle after he joins the crew.
Chaser: In Chaser's adventure mode, get Chaser to Lv. 15 and use him once in battle.
Kuina: In Chaser's adventure mode, get Kuina to Lv. 15 and use her once in battle.
Zeff: In Chaser's adventure mode, get Zeff to Lv. 15 and use him once in battle.
Hawk-Eyes Mihawk: In Chaser's adventure mode, use him once in battle after he joins the crew.
Support Characters: In adventure mode, use a support character in 3 battles, then they can be used by any character in Grand Battle mode.
Luffy 2P: Obtain the bonus item "Pirate Coat" by beating Crocodile the first time at Alubarna in the Alabasta Kingdom Sea area with a super attack
Luffy 4P: Obtain the bonus item "Cool Shades" by beating Buggy with an item at Orange Village in the Orange Village Sea area
Zolo 2P: Obtain the bonus item "Goggles" by beating Arlong at Spice Village in the Jaya Sea area
Zolo 4P: Obtain the bonus item "Necklace" by staying alive for 30 counts against Hawk-eye Mihawk at Blue Town in the Syrup Village Sea area
Sani 2P: Obtain the bonus item "Gaudy Shirt" by beating Don Krieg at Vinegar Village in the Jaya Sea area with Sanji
Sanji 4P: Obtain the bonus item "Necklace" by beating Chopper at Big Horn in the Drum Kingdom Sea area with Sanji
Nami 2P: Obtain the bonus item "Yellow T-shirt" by beating Buggy at Vermillion Town in Jaya Sea Area with Nami
Nami 4P: Obtain the bonus item "Fashionable Sunglasses" by beating Chaser at Navy Base No.64 in the Inshore Alabasta Kingdom area
Usopp 2P: Obtain the bonus item "White Bandana" by beating Kuro at Mock Town in the Jaya Sea area
Usopp 4P: Obtain the bonus item "Sunglasses" by beating Nami at Coco Village without knocking her out
Chopper 2P: Obtain the bonus item "Santa Hat" by beating Ace(Trace) with Chopper at a Wrecked Ship in the Graveyard of Ships
Chopper 4P: Obtain the bonus item "Panda T-shirt" by beating Nico Robin with Chopper at Erumalu in Alabasta Kingdom Sea area
Robin 2P: Obtain the bonus item "White Hat" by beating Ohm the first time at the Ruins in Skypiea
Luffy 3P: Obtain the bonus item "Baseball Uniform" by beating Luffy with more than 30% HP at Mustard Village in the Fusha Village Sea Area
Zolo 3P: Obtain the bonus item "Judo Wear" by beating Zolo with a super attack at Red Town in the Fusha Village Sea Area
Sanji 3P: Obtain the bonus item "Soccer Uniform" by beating Sanji without jumping at Carmine Town in the Orange Sea Area
Usopp 3P: Obtain the bonus item "Chestpiece" by beating Usopp without getting knocked down.
Nami 3P: Obtain the bonus item "Cheerleader" by beating Nami with more than 70% HP at Coco Village in the Roguetown Sea Area
Robin 3P: Obtain the bonus item "Kimono" by beating Nico Robinwith more than 50% HP at Misty Peak in the Drum Kingdom Sea area
Chopper 3P: Obtain the bonus item "Polo Shirt" by beating Chopper in 20 counts at Pepper Village in the Drum Kingdom Sea Area
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